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Nucleophilicity

Term · Chemistry · MLC-T-CHM-008139

A measure of the ability of a nucleophile to donate an electron pair and form a new bond with an electrophile. It is a kinetic property, reflecting the rate at which a nucleophile reacts. Factors influencing nucleophilicity include charge, electronegativity, steric hindrance, and solvent effects.

Table 1. Record
IdentifierMLC-T-CHM-008139
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1146 (https://doi.org/10.1351/pac199466051077)
See alsoLewis base; Lewis basicity; Ritchie equation; Swain-Scott equation; Electrophilicity; Nucleophile; Power; Order of reaction
Record as JSON
{
  "id": "MLC-T-CHM-008139",
  "term": "Nucleophilicity",
  "field": "Chemistry",
  "definition": "A measure of the ability of a nucleophile to donate an electron pair and form a new bond with an electrophile. It is a kinetic property, reflecting the rate at which a nucleophile reacts. Factors influencing nucleophilicity include charge, electronegativity, steric hindrance, and solvent effects.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Lewis base",
    "Lewis basicity",
    "Ritchie equation",
    "Swain-Scott equation",
    "electrophilicity",
    "nucleophile",
    "power",
    "order of reaction"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1146 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/nucleophilicity/"
}

Record 8,646 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.