Spin trapping
Term · Chemistry · MLC-T-CHM-011206
A technique used to detect and identify highly reactive free radicals by reacting them with a diamagnetic spin trap molecule to form a more stable, persistent radical adduct. This adduct, often a nitroxide, can then be characterized by electron paramagnetic resonance (EPR) spectroscopy. It is widely used in biological and chemical systems.
| Identifier | MLC-T-CHM-011206 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1166 (https://doi.org/10.1351/pac199466051077) |
| See also | Adduct; Attachment; Diamagnetic; Monitoring; Nitrones; Nitroso compounds; Persistent; Radical; Reactive; Spectroscopy; Transient species; Trapping |
Record as JSON
{
"id": "MLC-T-CHM-011206",
"term": "Spin trapping",
"field": "Chemistry",
"definition": "A technique used to detect and identify highly reactive free radicals by reacting them with a diamagnetic spin trap molecule to form a more stable, persistent radical adduct. This adduct, often a nitroxide, can then be characterized by electron paramagnetic resonance (EPR) spectroscopy. It is widely used in biological and chemical systems.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"adduct",
"attachment",
"diamagnetic",
"monitoring",
"nitrones",
"nitroso compounds",
"persistent",
"radical",
"reactive",
"spectroscopy",
"transient species",
"trapping"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1166 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/spin-trapping/"
}
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